Department of Chemistry

Midwestern State University         

Phone: 940-397-4463 (office)

E-Mail: jianguo.shao@mwsu.edu

Building/Room: Bolin - Room 307E



TEACHING LINKS

  CHEM 1141 (General Chem I Lab)                   
 
  CHEM 1143 (General Chem I Lecture)

  CHEM 1241 (General Chem II Lab)                  
 
  CHEM 1243 (General Chem II Lecture)
 
  CHEM 3305 (Analytical Chem I Lecture & Lab)

  CHEM 3405 (Analytical Chem II Lecture & Lab)
  
  CHEM 3504 (Intro Environmental Chem Lecture & Lab)

  CHEM 4505 (Environmental Chem Technology & Lab)

  CHEM 4001 (Chemistry Seminar)


WEB-LINK FOR PRE-PROFESSIONAL STUDENTS:

http://scienceandmath.mwsu.edu/preprofessional/


RESEARCH INTERESTS

Analytical Chemistry; Electrochemistry and Spectroelectrochemistry of Macrocyclic Compounds such as Porphyrins, Phthalocyanines, Porphyrazines and Corroles; Heterogeneous Catalysis; Zeolite Chemistry; Environmental Chemistry



RECENT PUBLICATIONS

1) Jianguo Shao, Kema Richards, Dwayne Rawlins, Baocheng Han, Christopher A. Hansen, "Synthesis, Electrochemistry, Spectroelectrochemistry and Catalytic Properties in DDT Reductive Dechlorination of Iron(II) Phthalocyanine, 2,3- and 3,4-Tetrapyridinoporphyrazine Complexes", Submitted to J. of Porphyrins and Phthalocyanines, 2013.

2) Jianguo Shao, Rina Kuwahara, DDT Dechlorination Electrocatalyzed by a Synthetic Iron Porphyrin in Pyridine, Texas J. of Science, in press, 2012.

3) Jianguo Shao, Abegayl Thomas. Baocheng Han, Christopher A. Hansen, “DDT Reductive Dechlorination Catalyzed by Cobalt Phthalocyanine, 2,3- and 3,4-tetrapyridoporphyrazine Complexes in Nonaqueous Media”, J. of Porphyrins and Phthalocyanines, 2010, 14, 133 - 141.

4) Jianguo Shao, Juliette Commodore, Baocheng Han, Cynthia Pruente, Christopher A. Hansen, “Electrochemical, Spectroelectrochemical and ESR Spectroscopic Characterization of 2,3- and 3,4-Cobalt Tetrapyridoporphyrazine Isomers in Nonaqueous Media”. J. of Porphyrins and Phthalocyanines, 2009, 13, 876 - 887.

5) Kumar, Mukesh; Cervantes-Lee, Francisco; Pannell, Keith H.; Shao, Jianguo, “Synthesis and Cyclic Voltammetric Studies of the Diiron Complexes ER2[(h5-C5H4)Fe(L2)Me]2 (E = C, Si, Ge, Sn, R = H, alkyl; L2 = diphosphine) and (h5-C5H4)Fe(h5-C5H5))”. Organometallics, 2008, 27(18), 4739 – 4748.

6) Shen, Jing; El Ojaimi, Maya; Chkounda, Mohammed; Gros, Claude P.; Barbe, Jean-Michel; Shao, Jianguo; Guilard, Roger; Kadish, Karl M., “Solvent, Anion, and Structural Effects on the Redox Potentials and UV-visible Spectral Properties of Mononuclear Manganese Corroles”. Inorg. Chem., 2008, 47(17), 7717-7727.

7) Sintic, Paul J.; E, Wenbo; Ou, Zhongping; Shao, Jianguo; McDonald, James A.; Cai, Zheng-Li; Kadish, Karl M.; Crossley, Maxwell J.; Reimers, Jeffrey R., “Control of the site and potential of reduction and oxidation processes in p-expanded quinoxalinoporphyrins”. Phys. Chem. Chem. Phys., 2008, 10(4), 268-280.

8) E, Wenbo; Kadish, Karl M.; Sintic, Paul J.; Khoury, Tony; Govenlock, Linda J.; Ou, Zhongping; Shao, Jianguo; Ohkubo, Kei; Reimers, Jeffrey R.; Fukuzumi, Shunichi; Crossley, Maxwell J., “Control of the Orbital Delocalization and Implications for Molecular Rectification in the Radical Anions of Porphyrins with Coplanar 90o and 180o b, b'-Fused Extensions”. J  Phys. Chem. A, 2008, 112(3), 556-570.

9) Kadish, Karl M.; E, Wenbo; Sintic, Paul J.; Ou, Zhongping; Shao, Jianguo; Ohkubo, Kei; Fukuzumi, Shunichi; Govenlock, Linda J.; McDonald, James A.; Try, Andrew C.; Cai, Zheng-Li; Reimers, Jeffrey R.; Crossley, Maxwell J., “Quinoxalino[2,3-b']porphyrins Behave as p-Expanded Porphyrins upon One-Electron Reduction: Broad Control of the Degree of Delocalization through Substitution at the Macrocycle Periphery”, J  Phys. Chem. B, 2007, 111(30), 8762-8774.

10) Jing Shen, Zhongping Ou, Jianguo Shao, Michal Galezowski, Daniel T. Gryko and Karl M. Kadish, “Free-Base Corroles: Determination of Deprotonation Constants in Non-aqueous Media”, J. of Porphyrins and Phthalocyanines, 2007, 11, 269-276.

11) Zhongping Ou, Jing Shen, Jianguo Shao, Wenbo E, Michal Galezowski, Daniel T. Gryko, and Karl M. Kadish, “Protonated Free-Base Corroles: Acidity, Electrochemistry, and Spectroelectrochemistry of [(Cor)H4]+, [(Cor)H5]2+, and [(Cor)H6]3+”, Inorg. Chem. 2007, 46, 2775 – 2786.

12) Ohkubo, K.; Sintic, P. J.; Tkachenko, N. V.; Lemmetyinen, H.; E, W.; Ou, Z.; Shao, J.; Kadish, K. M.; Crossley, M. J.; Fukuzumi, S. Chem. Phys., 2006, 326, 3-14.

13) Jing Shen, Jianguo Shao, Zhongping Ou, Wenbo E, Beata Koszarna, Daniel T. Gryko, Karl M. Kadish, “Electrochemistry and Spectroelectrochemistry of meso-Substituted Free-Base Corroles in Nonaqueous Media.  Reactions of (Cor)H3, [(Cor)H4]+ and [(Cor)H2]- ”, Inorg. Chem. 2006, 45, 2251-2265.

14) Kadish, K. M.; Shao, J.; Ou, Z., Zhan, R.; Burdet, F.; Barbe, J- M.; Gros, C. P.; Guilard, R., “Electrochemistry and Spectroelectrochemistry of Heterobimetallic Porphyrin-Corrole Dyads. Influence of Spacer, Metal Ion and Oxidation State on Pyridine Binding Ability”, Inorg. Chem. 2005, 44, 9023-9038.

15) Kadish, K. M.; Shao, J.; Ou, Z., Fremond, L.; Zhan, R.; Burdet, F.; Barbe, J- M.; Gros, C. P.; Guilard, R., “Electrochemistry, Spectroelectrochemistry, Chloride Binding, and O2 Catalytic Reactions of Free-Base Porphyrin-Cobalt Corrole Dyads”, Inorg. Chem. 2005, 44, 6744-6754.

16) Jiang, Z.; Ou, Z.; Chen, N.; Wang, J.; Huang. J.; Shao, J.; Kadish, K. M., “Synthesis, Spectral and Electrochemical Characterization of Non-aggregating a-Substituted Vanadium(IV)-oxo Phthalocyanines”, J. of Porphyrins and Phthalocyanines, 2005, 9, 352-360.

17) Guilard, R.; Burdet, F.; Barbe, J- M.; Gros, C. P.; Espinosa, E.; Shao, J.; Ou, Z.; Zhan, R.; Kadish, K. M., “Heterobimetallic Complexes of Cobalt(IV) Porphyrin-Corrole Dyads. Synthesis, Physicochemical Properties, and X-ray Structural Characterization”, Inorg. Chem. 2005, 44, 3972-3983.

18) Ou, Z.; E, Wenbo; Shao, J.; Burn, P. L.; Sheehan, C. S.; Walton, R.; Kadish, K. M.; Crossley, M. J., “Electrochemical and Spectroelectrochemical Properties of Building Blocks for Molecular Arrays: Reactions of Quinoxalino[2,3-b]porphyrins Containing Metal(II) Ions”, J. of Porphyrins and Phthalocyanines, 2005, 9, 142-152.

19) Kadish, K. M.; Fremond, L.; Ou, Z.; Shao, J.; Shi, C.; Anson, F. C.; Burdet, F.; Gros, C. P.; Barbe, J-M.; Guilard, R., “Cobalt(III) Corroles as Electrocatalysts for the Reduction of Dioxygen: Reactivity of a Monocorrole, Biscorroles, and Porphyrin-Corrole Dyads”, J. Am. Chem. Soc. 2005, 127, 5625-5631.

20) Zhongping Ou, Jianguo Shao, Hui Zhao, Kei Ohkubo, Ingar H. Wasbotten, Shunichi Fukuzumi, Abhik Ghosh, Karl M. Kadish, “Spectroelectrochemical and ESR studies of highly substituted copper corroles”, J. of Porphyrins and Phthalocyanines,  2004, 8, 1236-1247.

21) Baocheng Han, Jianguo Shao, Zhongping Ou, Tuan D. Phan, Jing Shen, John L. Bear, Karl M. Kadish, “Synthesis and Characterization of Nitrosyl Diruthenium Complexes. Interaction between NO and CO across the Metal-Metal Bond”, Inorg. Chem., 2004, 43, 7741-7751.

22) Roger Guilard, Francois Jerome, Jean-Michel Barbe, Claude P. Gros, Enrique Espinosa, Jianguo Shao, Zhongping Ou, Jean Fisher, Raymond Weiss, Karl M. Kadish, “Aryl and Aryl Substituted Corroles. 5. Synthesis and Characterization of Bis-Copper Complexes”, Inorg. Chem., 2004, 43, 7441-7455.

23) Zhongping Ou; Karl M. Kadish; Wenbo E; Jianguo Shao; Paul J. Sintic; Kei Ohkubo; Shunichi Fukuzumi and Maxwell J. Crossley, “Substituent Effects on the Site of Electron Transfer During the First Reduction for Gold(III) Porphyrins”, Inorg. Chem., 2004, 43, 2078-2086.

24) Kei Ohkubo; Hiroaki Kotani; Jianguo Shao; Zhongping Ou, Karl M. Kadish; Guolin Li; Ravindra K. Pandey; Mamoru Fujitsuka; Osamu Ito; Hiroshi Imahori and Shunichi Fukuzumi, “Ultra-Long Lived Charge-Separated in Zinc Chlorin-C60 Dyad Produced by One-Step Photoinduced Electron Transfer”, Angew. Chem., Int. Ed., 2004, 43, 853-856.

25) Karl M. Kadish; Tuan D. Phan; Lingamallu Giribabu; Jianguo Shao; Li-Lun Wang; Antoine Thuriere; Eric Van Caemelbecke; John L. Bear, “Electrochemical and Spectroelectrochemical Characterization of Ru24+ and Ru23+ Complexes Under a CO Atmosphere”, Inorg. Chem. 2004, 43, 1012-1020.

26) Shunichi Fukuzumi; Kei Ohkubo; Wenbo E; Zhongping Ou; Jianguo Shao; Karl M. Kadish; James A. Hutchison; Kenneth P. Ghiggino; Paul J. Sintic and Maxwell J. Crossley, “Metal-Centered Photoinduced Electron Transfer Reduction of a Gold(III) Porphyrin Cation Linked with a Zinc Porphyrin to Produced a Long-Lived Charge-Separated State in Nopolar Solvents”, J. Am. Chem. Soc., 2003, 125, 14984-14985.



RECENT PRESENTATIONS

1) Matlock Baggett, Jianguo Shao, Christopher A. Hansen, Synthesis, Electrochemical and UV-visible Spectroscopic Characterizations of Tetraphenylazadipyrromethene Complexes, the Third Annual Scholarship Colloquium at Midwestern State University, 2012, Poster.

2) Mbwidiffu Malgwi, Donald Fru, Jianguo Shao, Christopher A. Hansen, Synthesis, electrochemical and spectroscopic characterization and DDT catalytic dechlorination of a cobalt tetrapyrazinoporphyrazine complex, the Third Annual Scholarship Colloquium at Midwestern State University, 2012, Poster.

3) Dopp Jared, Christopher A. Hansen, Jianguo Shao, Synthesis of a Dipyridinium Ion, the 57th Oklahoma Pentasectional Meeting of the American Chemical Society, Lawton, OK, 2012, Poster.

4) Matlock Baggett, Jianguo Shao, Christopher A. Hansen, Synthesis, Electrochemical and UV-visible Spectroscopic Characterizations of Tetraphenylazadipyrromethene Complexes, the 57th Oklahoma Pentasectional Meeting of the American Chemical Society, Lawton, OK, 2012, Oral Presentation.

5) Mbwidiffu Malgwi, Donald Fru, Jianguo Shao, Christopher A. Hansen, Synthesis, electrochemical and spectroscopic characterization and DDT catalytic dechlorination of a cobalt tetrapyrazinoporphyrazine complex, the 67th Southwest Regional Meeting of the American Chemical Society, Austin, TX, 2011, Poster# 423.

6) Kema Richards, Dwayne Rawlins, Jianguo Shao, Christopher A. Hansen, DDT Degradation Catalyzed by Metal-Centered Macrocyclic Complexes in Pyridine, the Second Annual Scholarship Colloquium at Midwestern State University, 2011, Poster.

7) Halima Sani, Pinkal Patel, Christopher A. Hansen, Jianguo Shao, Synthesis, Electrochemistry and Spectroscopic Properties of 2,3-Mn-PyD and 3,4-Mn-PyD, the second  Annual Scholarship Colloquium at Midwestern State University, 2011, Poster.

8) Kema Richards, Dwayne Rawlins, Jianguo Shao, Christopher A. Hansen, DDT Degradation Catalyzed by Iron Phthalocyanine, 2,3-Fe-PyD and 3,4-Fe-PyD Complexes, the 114th Annual Meeting of the Texas Academy of Science, Austin, TX, 2011, Oral Presentation.

9) Halima Sani, Pinkal Patel, Christopher A. Hansen, Jianguo Shao, Synthesis, Electrochemistry and Spectroscopic Properties of Manganese(II) Macrocyclic Complexes, the 114th Annual Meeting of the Texas Academy of Science, Austin, TX, 2011, Oral Presentation.

10) Dwayne Rawlins, Christopher A. Hansen, Jianguo Shao, Synthesis, Electrochemistry and Spectroscopic Properties of 2,3-Fe-PyD and 3,4-Fe-PyD, the First Annual Scholarship Colloquium at Midwestern State University, 2010, Oral Presentation.

11) Kema Richards, Jianguo Shao, Christopher A. Hansen, Synthesis, Electrochemistry and Spectroscopic Properties of 3,4-Ni(II)-PyD, the First Annual Scholarship Colloquium at Midwestern State University, 2010, Poster.

12) Jonpaul Wright, Jianguo Shao, Christopher A. Hansen, Synthesis, electrochemistry and spectroscopic properties of 2,3-Ni(II) PyD, the First Annual Scholarship Colloquium at Midwestern State University, 2010, Poster.

13) Sheldon Hilaire, Jianguo Shao, Christopher A. Hansen, Synthesis, Electrochemistry and Spectroscopic Properties of Co(II) Tetrapyrazinoporphyrazine, the First Annual Scholarship Colloquium at Midwestern State University, 2010, Poster.

14) Dwayne Rawlins, Christopher A. Hansen, Jianguo Shao, “Synthesis, Electrochemistry and UV-Visible Spectroscopic Properties of Iron(II) Tetrapyridoporphyrazines”, the 64th Southwest Regional Meeting of the American Chemical Society, Little Rock, AR, 2008, Oral presentation, Abstract# 258.

15) Abegayl Thomas, Jianguo Shao, Christopher A. Hansen, “DDT Dechlorination Catalyzed by Cobalt Pyridino-porphyrazines”, the 2008 Oklahoma ACS Pentasectional Meeting, Duncan, OK, 2008, Abstract# E-05.

16) Dwayne Rawlins, Abegayl Thomas, Jianguo Shao, “DDT Dehalogenation Catalyzed by Metalloporphyrins in Pyridine”, the 2008 Oklahoma ACS Pentasectional Meeting, Duncan, OK, 2008, Abstract# E-06.

17) Abegayl Thomas, Jianguo Shao, Christopher A. Hansen, “DDT Dechlorination Reaction Catalyzed by Cobalt Tetrapyridinoporphyrazine Complexes in Pyridine Solution” the 234th ACS Meeting, Boston, 2007, Abstract# CHED 178.

18) Jianguo Shao, Juliette Commodore, Baocheng Han, Christopher Hansen, “Electrochemical and Spectroelectrochemical Characterization of Cobalt Tetrapyridinoporphyrazine compounds in DMSO solution”, the 234th ACS Meeting, Boston, 2007, Abstract# CHED 180.                                  


Return to MSU home